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A way to enantiopure 1,4-oxazepanes91189126, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8742]], camposKey:1477-0520 2014-01-01 Tandem diastereo- and enantioselective preparation of aryl and alkyl cyclopropyl carbinols with three adjacent stereocenters using perhydrobenzoxazines and diethylzinc345354, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8744]], camposKey:1434-193X 2013-08-01 Enantioselective One-Pot Catalytic Synthesis of 4,5-Epoxy-3-alkanols and 1-Phenyl-2,3-epoxy-1-alkanols from alpha,beta-Unsaturated Aldehydes48634869, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8743]], camposKey:1615-4150 2012-10-01 Enantiocontrolled Synthesis of Tertiary alpha-Hydroxy-alpha-ynyl Esters by Dimethylzinc-Mediated Addition of Alkynes to alpha-Keto Esters27972804, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8737]], camposKey:0039-7881 2012-05-01 Enantioselective Addition of Dimethylzinc to Aldehydes Catalyzed by a Chiral Perhydro-1,3-benzoxazine-Based Amino Alcohol as Ligand13431348, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8740]], camposKey:0947-6539 2012-04-01 Highly Homogeneous Stereocontrolled Construction of Quaternary Hydroxyesters by Addition of Dimethylzinc to alpha-Ketoesters Promoted by Chiral Perhydrobenzoxazines and B(OEt)(3)43754379, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8739]], camposKey:1477-0520 2011-01-01 Asymmetric additive-free aryl addition to aldehydes using perhydrobenzoxazines as ligands and boroxins as aryl source66916699, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8741]], camposKey:0957-4166 2010-09-27 Perhydro-1,3-benzoxazines derived from (-)-8-aminomenthol as ligands for the catalytic enantioselective addition of diethylzinc to aldehydes22302237, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=8738]], camposKey:0040-4020 2009-01-01 Lewis acid mediated diastereoselective keto-ene cyclization on chiral perhydro-1,3-benzoxazines: synthesis of enantiopure cis-3,4-disubstituted 3-hydroxypyrrolidines97289736, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2502]], camposKey:0022-3263 2006-11-10 Diastereoselective synthesis of enantiopure morpholines by electrophilic selenium-induced 6-exo cyclizations on chiral 3-allyl-2-hydroxymethylperhydro-1,3-benzoxazine derivatives88548863, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2509]], camposKey:1434-193X 2006-07-10 An efficient and diastereoselective intramolecular 1,3-dipolar cycloaddition of cyclic azomethine ylides and nitrones32593265, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2481]], camposKey:0022-3263 2006-07-07 1,4-asymmetric induction in methoxyselenenylation of double bonds at the nitrogen side of chiral perhydro-1,3-benzoxazines promoted by nonbonded Se center dot center dot center dot N interactions53885391, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2503]], camposKey:0022-3263 2006-03-17 Regio- and stereoselective methoxyselenenylation of chiral 2-vinyl perhydro-1,3-benzoxazines promoted by selenium-heteroatom nonbonded interactions24242428, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2476]], camposKey:1434-193X 2005-06-13 Sequential diastereoselective addition of allylic and homoallylic grignard reagents to 2-acyl-perhydro-1,3-benzoxazines and ring-closing metathesis: an asymmetric route to azepin-3-ol and azocin-3-ol derivatives24492458, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2479]], camposKey:0022-3263 2005-02-18 Diastereoselective Yang photocyclization reactions in solution. 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A rapid entry to enantiopure cis-3,4-disubstituted pyrrolidines43324337, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2493]], camposKey:0957-4166 2003-10-03 Regio- and diastereoselective tandem addition-carbocyclization promoted by sulfanyl radicals on chiral perhydro-1,3-benzoxazines29852990, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2498]], camposKey:0022-3263 2003-06-13 Synthesis of enantiopure 3-azabicyclo[3.2.0]heptanes by diastereoselective intramolecular [2+2] photocycloaddition reactions on chiral perhydro-1,3-benzoxazines49234931, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2457]], camposKey:0022-3263 2003-03-07 Temperature- and time-dependent stereochemical control in thermally induced keto-ene cyclizations18521858, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2500]], camposKey:0039-7881 2003-01-01 Total regio- and stereoselective synthesis of perhydropyrrolo[3,4-c]pyrazole derivatives by [3+2] intramolecular dipolar cycloaddition reaction on chiral perhydro-1,3-benzoxazines14571461, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2494]], camposKey:1523-7060 2002-07-25 A novel synthesis of enantiopure octahydropyrrolo[3,4-b]pyrroles by intramolecular [3+2] dipolar cycloaddition on chiral perhydro-1,3-benzoxazines25132516, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2482]], camposKey:0957-4166 2002-02-13 Synthesis of the novel chiral 1,3-amino alcohol 8-N,N-bis(ferrocenylmethyl)amino-menthol and its use as catalyst in the enantioselective addition of diethylzinc to aldehydes58, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2505]], camposKey:0022-3263 2002-02-08 Stereocontrolled IMDA reaction of styrene derivatives. A way to enantiopure 3a,4,9,9a-tetrahydrobenz[f]isoindolines782789, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2412]], camposKey:0936-5214 2002-02-01 Unexpected rearrangement in the heck cyclization of positional isomers of chiral 2,3-disubstituted perhydro-1,3-benzoxazines259262, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=54801]], camposKey:0931-7597 2002-01-01 ChemInform Abstract: A Novel Synthesis of Enantiopure Octahydropyrrolo[3,4-b]pyrroles by Intramolecular [3 + 2] Dipolar Cycloaddition on Chiral Perhydro-1,3-benzoxazines00, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2458]], camposKey:0040-4020 2001-04-30 Synthesis of enantiopure mono- and disubstituted tetrahydroisoquinolines by 6-exo radical cyclizations40054014, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2504]], camposKey:0002-7863 2001-03-07 Diastereoselective tandem 6-exo carbolithiation intramolecular ring opening in (-)-8-aminomenthol-derived perhydrobenzoxazines. 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A novel entry to enantiopure morpholines893895, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2478]], camposKey:0022-3263 2000-02-11 A short diastereoselective synthesis of enantiopure highly substituted tetrahydroepoxyisoindolines831839, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2507]], camposKey:0022-3263 1999-07-09 Thermal and Lewis acid catalyzed diastereoselective intramolecular Diels-Alder reaction on alpha,beta-unsaturated amides derived from (-)-8-aminomenthol52305236, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2433]], camposKey:0022-3263 1999-06-11 A novel approach to chiral, nonracemic pyrrolidines by 5-exo-trig diastereoselective radical cyclization on acrylamides derived from(-)-8-aminomenthol42824288, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2470]], camposKey:0022-3263 1999-06-11 Regio- and stereoselective 5-exo radical cyclizations on a chiral perhydro-1,3-benzoxazine moiety. An access to enantiopure 3-alkylpyrrolidines42734281, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2454]], camposKey:0040-4039 1999-03-19 Synthesis of enantiopure 3-alkyl-perhydroazepines by diastereoselective 7-endo-radical cyclisation on a chiral 1,3-perhydrobenzoxazine derivative24212424, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2449]], camposKey:1359-7345 1999-01-07 Tributyltin radical-induced addition-carbocyclization on chiral perhydro-1,3-benzoxazines: a facile entry to enantiopure tin-containing auxiliaries3132, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2474]], camposKey:0022-3263 1998-11-13 Synthesis of enantiopure highly substituted trans-8a-hydroxydecahydroisoquinolines by sequential diastereoselective IMDA reaction and oxanorbornene nucleophilic ring opening85708573, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2444]], camposKey:0936-5214 1997-12-01 Unexpected stereoselective 6-exo versus 7-endo aryl radical cyclisation controlled by positional isomers in a chiral octahydro-1,3-benzoxazine moiety13911392, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2508]], camposKey:0040-4039 1997-02-24 Diastereoselective intramolecular Diels-Alder reaction of the furan diene, a facile access to enantiopure epoxy tetrahydroisoindolines.14631466, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2461]], camposKey:0040-4039 1996-12-09 Diastereoselective 5-exo-trig radical cyclisation on N-acryloyl-tetrahydro-1,3-oxazines. A novel approach to enantiopure 3-substituted pyrrolidines90859086, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2484]], camposKey:0022-3263 1996-06-14 Synthesis of enantiopure primary amines by stereoselective ring opening of chiral octahydro-1,3-benzoxazines by grignard and organoaluminum reagents41304135, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2467]], camposKey:0040-4039 1993-12-17 A NOVEL HIGHLY DIASTEREOSELECTIVE SYNTHESIS OF CYANO ETHERS BY REGIOSELECTIVE RING-OPENING OF CHIRAL OXAZOLIDINIUM METHIODIDES WITH SODIUM-CYANIDE83258328, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2424]], camposKey:1130-2283 1993-01-01 CHIRAL AMINE-BORANES DERIVED FROM EPHEDRINE AND PSEUDOEPHEDRINE AS ASYMMETRIC REDUCTION AND HYDROBORATION REAGENTS - STERICAL RELATIONSHIP TO THE MECHANISM OF THE REACTIONS629632, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2495]], camposKey:0040-4039 1992-08-11 A NEW CHIRAL GLYCINE SYNTHON - SYNTHESIS, X-RAY STRUCTURE OF (-)BULLET(2S,4R)-2-ETHOXYCARBONYL-4-PHENYL-1,3-OXAZOLIDINE AND DIASTEREOSELECTIVE NUCLEOPHILIC RING-OPENING TO (R)-ETHYL ALPHA-AMINO CARBOXYLATES47434746, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2406]], camposKey:0040-4039 1992-05-12 STEREOSELECTIVE RING-OPENING OF CHIRAL OXAZOLIDINES BY REFORMATSKY REAGENTS - AN ENANTIOSELECTIVE ENTRY TO BETA-AMINO ESTERS28952898, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2420]], camposKey:0039-7911 1992-01-01 REDUCTIVE RING-OPENING OF EPHEDRINE AND PSEUDOEPHEDRINE-DERIVED OXAZOLIDINIUM METHIODIDES BY SODIUM-BOROHYDRIDE - A DIRECT ACCESS TO NEW CHIRAL AMINE-BORANE ADDUCTS829839, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=46786]], camposKey:0936-5214 1992-01-01 Regio- and stereocontrolled nucleophilic ring opening of chiral oxazolidines by diethylaluminum cyanidea short and efficient route to enantiomerically enriched ¿-Amino Esters4547, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2442]], camposKey:0936-5214 1992-01-01 REGIOCONTROLLED AND STEREOCONTROLLED NUCLEOPHILIC RING-OPENING OF CHIRAL OXAZOLIDINES BY DIETHYLALUMINUM CYANIDE - A SHORT AND EFFICIENT ROUTE TO ENANTIOMERICALLY ENRICHED ALPHA-AMINO ESTERS4547, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=68811]], camposKey:0936-5214 1990-12-01 Diastereoselective ring opening of 2-substituted n-benzyl-4,4, 7¿-trimethyl-trans-octahydro-1,3-benzoxazines by grignard reagents. highly enantioselective synthesis of primary amines763765, com.sigma.fs3.argos.domain.gpc.GpcArticlesRev[id=com.sigma.fs3.argos.domain.gpc.GpcArticlesRevPK[ifcactivitat=ARE, ifccomptador=2466]], camposKey:0936-5214 1990-12-01 DIASTEREOSELECTIVE RING-OPENING OF 2-SUBSTITUTED N-BENZYL-4,4,7-ALPHA-TRIMETHYL-TRANS-OCTAHYDRO-1,3-BENZOXAZINES BY GRIGNARD-REAGENTS - 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